Reaction; Knoevenagel Condensation; Reformatsky Reaction; Robinson Annulation. 38-62 (1942); B. Eistert in Newer Methods in Preparative Organic Chemistry vol. 1 (Interscience, New York, 1948) Free radical mediated ring expansions of haloalkyl β-ketoesters: Synthetic C. Masters, Adv. Organomet. Chem. 17, 61
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Organic Chemistry II Andrew Rosen April 2, 2013 Contents Grignard reagents or organolithium reagents can convert a nitrile to a ketone. Examples are shown below: 1.4 Synthesis of Ketone Example Note that PBr 3 replaces an OH with a Br and does not have rearrangements It is useful for creating alkyl bromides, which can then make grignard
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